Product ID:M-114 M
MSDS Date:11/08/1993
FSC:6850
NIIN:00N059320
MSDS Number: BXJJY

FINE ORGANICS CORP

205 MAIN ST
LODI, NJ 07644
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 201-472-6800

Cage: 05867

FINE ORGANICS CORP

2277 CLIFTON, NJ 07015 US

Telephone: 973-478 1000

Cage: 05867

METHANE, DICHLORO-; (METHYLENE CHLORIDE) (SARA 313)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 69%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM, A2

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHANE, 1,1,1-TRICHLORO-; (METHYL CHLOROFORM) (SARA 313)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 21%

OSHA PEL 350 PPM

ACGIH TLV: 350 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA 313) (CERCLA)

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 10%

OSHA PEL 200 PPM

ACGIH TLV: 200 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

FORMATION OF HCL AND/OR PHOSGENE .

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATLS HAVE PRDCED SENSIT
OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR
EFT IN HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE
CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINI NG USES IN HUMANS
ACUTELY/CHRONICALLY EXPOSED TO CHLOROCARBONS . INHAL:HIGH VAP CONCS
ARE IRRIT (EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE:IARC MONOGRAPHS SUPP,
VOL 7, PG 194, 1987:GROUP 2B. NTP 7TH ANNUAL RPT ON CARCINS,
1994:ANTIC(SUPDAT)
Effects of Overexposure:HLTH HAZS:TO RESP TRACT & MAY CAUSE HDCHS,
DIZZ, DROW, UNCON & OTHER CNS EFTS. EYE:CONT WILL CAUSE IRRIT.
SKIN:MAY CAUSE IRRIT &/OR DERM. INGEST:MAY LEAD TO PULM INJURY IF
ASPIR INTO LUNGS. CHRONIC:PR OD MAY AFFECT FOLLOWING ORGANS:LIVER &
KIDNEYS.
Medical Cond Aggravated by Exposure:PRE-EXISTING LIVER AND KIDNEY
DISEASES.

First Aid:INHAL:REMOVE TO FRESH AIR. ADMIN ARTF RESP IF BRTHG HAS
STOPPED. SEEK MED ATTN IN NEC INSTANCES. EYES:FLUSH THORO W/WATER
FOR AT LST 15 MIN W/IN ONE MINUTE OF CONT. SKIN:WASH AREAS OF COT
W/GENEROUS A MTS OF WATER. REMOVE CONTAM CLTHG. LAUNDER BEFORE
REUSE. INGEST:DO NOT INDUCE VOMIT. GIVE PLENTY OF WATER. SEEK MED
ATTN IN ANY NECESSARY INSTANCES.

Flash Point Method:TCC
Flash Point:NONE
Lower Limits:1.8%
Upper Limits:11.5%
Extinguishing Media:CARBON DIOXIDE, FOAM OR SUITABLE DRY CHEMICAL
EXTINGUISHER.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
& FULL PROTECTIVE EQUIPMENT . FOLLOW PROCEDURES FOR HYDROCARBON
FIRE.
Unusual Fire/Explosion Hazard:DANGEROUS FIRE HAZARD WHEN EXPOSED TO
HEAT OR FLAME. THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE HCL AND
PHOSGENE .

Spill Release Procedures:IF OUTDOORS, ADD SAND, EARTH/OTHER SUITABLE
ABSORB TO SPILL AREA. KEEP PROD OUT OF SEWERS & WATER COURSES BY
DIKING/IMPOUNDING. INSIDE SPILLAGE, SHUT OFF/ELIM ALL IGNIT SOURCES
& REMOVE W/ABSORB MATL. SWEEP UP ABSORB MATL & FOLLOW WASTE DISP
METHODS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STOR TEMP:32-100F. STOR PRESS:NORMAL.
GEN:STORE INDOORS, IN TIGHTLY SEALED CNTNR. STORE IN COOL AREA,
AWAY FROM ALL SOURCES OF HEAT & IGNITION.
Other Precautions:EMPTIED CNTNRS MAY RETAIN HAZ RESIDUE & EXPLO VAPS.
KEEP AWAY FROM HEAT, SPKS & FLAMES. DO NOT CUT, PUNCTURE/WELD
ON/NEAR CNTNR. FOLLOW LBL WARNINGS UNTIL CNTNR IS THORO
CLEANED/DESTROYED. DO NOT USE IN POORLY VENT/CONFINED SPACES
(SUPDAT)

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATORY PROTECTION IN
ACCORDANCE W/29 CFR 1910.134 & ANSI Z88.2-1969 MUST BE WORN WHEN
THE CONCENTRATION OF HAZARDOUS MATERIALS ARE AT OR ABOVE THE TLV
SET BY ACGIH OR OSHA.
Ventilation:CTL AIRBORNE CONCS BELOW EXPOS GUIDELINES. USE ONLY W/ADEQ
VENT. LOC EXHST VENT MAY BE NEC FOR SOME OPERATIONS.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLAN OF CARCIN:TO BE CARCIN. ANIMAL:LUNG, LIVER, SALIVARY, MAMMRY
GLAND (TUMORS). OTHER PREC:W/OUT PROPER RESP PROT. DO NOT ATOMIZE.
USE EXHST VENT TO KEEP AIRBORNE CONCS BELOW EXPOS LIMS. NO SMKG I N
AREA OF USE. DO NOT USE IN GEN VICIN OF ARC WELDING, OPEN
FLAMES/HOT SURFS. HEAT &/OR UV RADIA MAY CAUSE (ING 4)

Boiling Pt:B.P. Text:106F,41C
Vapor Pres:282.5@20C
Vapor Density:>3.0
Spec Gravity:1.24 @ 25C
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID, MILDLY SWEET ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:OXIDES OF CARBON AND POSSIBLE TRACES
OF PHOSGENE. HCL .

Waste Disposal Methods:DISPOSE IN ACCORD W/42 USG325/ET. SEQ. RCRA
1976. DISPOSE IN ACCORD W/ALL LOC, STATE & FED REGS. DISP RECOMS
APPLY TO ORIGINAL MATL & ITS CNTNRS & NOT ANY MATLS WHICH ARE A
WASTE BY-PRODUCT OF THE USE R'S OPERATION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.